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- Name : Arsenic
- Symbol : As
- Atomic # : 33
- Atom weight: 74.9216
- Melting P. : 817
- Boiling P. : 613
- Oxidation : +3, -3, +5
- Pronounced : AR-s'n-ik
- From : Latin arsenicum, and Greek, arsenikon: both are names for a
- popular pigment, yellow orpiment
- Identified : Possibly by Albertus Magnus in 1250 A.D.
- Appearance : Steel gray, brittle semimetal
- Note : Popularly known for its highly poisonous compounds
-
- [Properties]
-
- Arsenic is a semimetal, or metalloid element. It isn't quite a metal such
- as aluminum or tin, and it isn't quite a nonmetal such as sulfur and bromine.
- It belongs to a fairly small group of semimetal that share the same general
- area on the periodic table of the elements.
- The principal allotrope of the arsenic is gray arsenic. This is
- characterized as a brittle, silvery-gray metal. Two other allotropes,
- yellow and black arsenic, are unstable crystalline substances that can be
- produced by first heating, then cooling, gray arsenic. Gray arsenic tends
- to sublimate rather than go through a molten state. Heating gray arsenic to
- its sublimation temperature, 613 degrees, causes it to generate an arsenic
- vapor. If you cool this vapor slowly, you will see the black form of
- arsenic condensing on the sample. As the sample continues to cool and
- passes through the 360 degrees mark, the blakc arsenic changes back to the
- gray form.
- Cooling gray arsenic rapidly from its sublimation temperature, however,
- causes yellow arsenic to condense on the sample. Unlike black arsenic, the
- yellow attotrope does not automatically return to the gray form upon
- further cooling. The yellow allotrope is stable with respect to changes in
- temperature but is sensitive to light. Light energy converts yellow arsenic
- to the stable gray form.
-